To unassign configuration baselines from clients in Configuration Manager 2007, delete the assignment from the configuration baseline properties.
To unassign a configuration baseline from a collection
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In the Configuration Manager console, navigate to System Center Configuration Manager / Site Database / Computer Management / Desired Configuration Management / Configuration Baselines.
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Right-click the configuration baseline that you want to unassign, and click Properties.
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In the Assignments tab, select the assignment you want to remove and click Delete.
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Click OK.
Note For more information about the options in the configuration baseline properties dialog box, see Configuration Baseline Properties.